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Production & Quality

Peroxide Value and K232/K268: The Chemistry of Olive Oil Freshness

5 min read 2025-09-15Europe Olive Oil

Quick Answer

Acidity alone isn't enough; measuring olive oil freshness also requires the peroxide value (≤20 mEq O2/kg for extra virgin, showing early-stage oxidation) and K232/K268 UV absorbance tests. A high K268 can signal that refined oil has been mixed into an "extra virgin" product. Europe Olive Oil records all three values for every production batch in an accredited laboratory.

Is Acidity Enough on Its Own?

Acidity is an important indicator but does not alone tell how fresh the oil is. For that the laboratory makes two more measurements: peroxide value and UV absorbance (K232, K268).

What Is the Peroxide Value?

Peroxides are the first products formed when oil begins to oxidise. So the peroxide value shows the early stage of oxidation.

  • Limit for extra virgin: ≤ 20 mEq O2/kg
  • A low value = fresh, properly stored oil
  • A high value = oil worn by air, light or heat

K232 and K268 (UV Absorbance)

These tests measure how much the oil absorbs ultraviolet light at certain wavelengths:

  • K232: reflects the early stage of oxidation
  • K268: reveals advanced oxidation and the presence of refined oil

A high K268 can be a sign that refined oil has been mixed into an "extra virgin" product, making it very valuable for detecting adulteration.

Why It Matters

Together, these three parameters reveal both the freshness and the purity of the oil. Saying "extra virgin" is not enough; real quality is proven by these numbers.

Europe Olive Oil's Approach

For every production batch, acidity, peroxide and UV values are recorded in an accredited laboratory. Transparency is the foundation of trust.

Europe Olive Oil: low acidity, low peroxide, 100% natural purity — backed by EL40296.

Frequently Asked Questions

Is olive oil with low acidity always fresh?+

No, acidity alone is not enough. To fully assess freshness, additional tests such as peroxide value and K232/K268 UV absorbance are also needed.

What does the peroxide value mean?+

Peroxides are the first products formed when oil begins to oxidise. The peroxide value shows the early stage of oxidation; the limit for extra virgin is ≤20 mEq O2/kg, with a low value indicating fresh, properly stored oil.

What do the K232 and K268 tests reveal?+

K232 reflects the early stage of oxidation, while K268 reveals advanced oxidation and the presence of refined oil. A high K268 can be a sign that refined oil has been mixed into an "extra virgin" product.

Why do these values matter for detecting adulteration?+

Simply saying "extra virgin" is not a quality guarantee; together acidity, peroxide and UV values prove both the freshness and purity of the oil and can reveal a refined-oil blend.

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